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Primary Pigments:
Monascorubrin (orange-red) and Rubropunctatin (red) – lipid-soluble azaphilone pigments.
Monascin (yellow) and Ankaflavin (yellow) – water-soluble derivatives.
Structure:
Azaphilone compounds with a pyranoquinone skeleton, highly stable under heat (up to 120°C) and pH 2–10.
Solubility:
Lipid-soluble pigments dissolve in ethanol, oils, and organic solvents.
Water-soluble forms (e.g., monascorubramine) generated in acidic/alkaline conditions.
Stability:
Resists light degradation better than synthetic dyes (e.g., Allura Red) due to conjugated polyketide chains.
Action | Functional Role |
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Natural Coloring | Replaces synthetic red dyes (e.g., in sausages, fish paste, sauces, and baked goods), providing vibrant red-to-orange hues. |
Antioxidant Activity | Scavenges free radicals (IC50 ≈ 80–110 μg/mL), inhibits lipid peroxidation, extending food shelf life. |
Antimicrobial Effect | Suppresses Staphylococcus aureus, Bacillus subtilis, and fungi via pigment-associated metabolites. |
Biofunctional Support | Synergizes with monacolin K (cholesterol-lowering) and GABA (antihypertensive) in fermented products. |
Food Industry:
Meat Processing: Colors sausages/hams while inhibiting Clostridium botulinum.
Dairy & Condiments: Used in cheeses, tomato sauces, and pickled vegetables.
Beverages: Stabilizes color in fruit drinks (pH 3–4).
Health Products:
Incorporated into capsules/gummies as a "clean-label" colorant with added antioxidant benefits.
Cosmetics:
Natural red pigment for lipsticks and blushes (non-toxic alternative to Carmine).